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Platinum
Platinum Element Facts You Need to Know
Platinum
Chemical & Physical Properties
by Anne Marie
Helmenstine, Ph.D.
Platinum is a transition metal that is highly valued for jewelry
and alloys. There are many interesting facts about this element.
Platinum Basic Facts
·
Atomic number: 78
·
Symbol: Pt
·
Atomic weight:
195.08
Discovery
It's difficult to assign credit for the discovery. Ulloa 1735
(in South America), Wood in 1741, Julius Scaliger in 1735 (Italy) can all make
claims to this honor.
Platinum was used in relatively pure form by the pre-Columbian
Native Americans.
Electron
configuration: [Xe] 4f14 5d9 6s1
Word Origin
"Platinum" comes from the Spanish word platina, meaning "little silver."
Isotopes
Six stable isotopes of platinum occur in nature (190, 192, 194,
195, 196, 198). Information on three additional radioisotopes is available
(191, 193, 197).
Properties
Platinum has a melting point of 1772 degrees C, the boiling
point of 3827 +/- 100 degrees C, the specific gravity of 21.45 (20 degrees C),
with a valence of 1, 2, 3, or 4.
Platinum is a ductile and malleable silvery-white metal. It does
not oxidize in air at any temperature, although it is corroded by cyanides,
halogens, sulfur, and caustic alkalis.
Platinum does not dissolve in hydrochloric or nitric acid but
will dissolve when the two acids are mixed to form aqua regia.
Uses
Platinum is used in jewelry, wire, to make crucibles and vessels
for laboratory work, electrical contacts, thermocouples, for coating items that
must be exposed to high temperatures for long periods of time or must
resist corrosion,
and in dentistry.
Platinum-cobalt alloys have interesting magnetic properties.
Platinum absorbs large amounts of hydrogen at room temperature,
yielding it at red heat. The metal is often used as a catalyst.
The platinum wire will glow red-hot in the vapor of methanol,
where it acts as a catalyst, converting it to formaldehyde.
Hydrogen and oxygen will explode in the presence of platinum.
Where to Find It
Platinum occurs in native form, usually with small amounts of
other metals belonging to the same group (osmium, iridium, ruthenium,
palladium, and rhodium).
Another source of the metal is sperrylite (PtAs2).
Element Classification
Platinum Physical Data
·
Density (g/cc): 21.45
·
Melting point (K): 2045
·
Boiling point (K): 4100
·
Appearance: Very heavy, soft, silvery-white metal
·
Atomic radius (pm): 139
·
Atomic volume (cc/mol): 9.10
·
Covalent radius (pm): 130
·
Ionic radius: 65 (+4e) 80 (+2e)
·
Specific heat (@20 degrees C J/g mol): 0.133
·
Fusion heat (kJ/mol): 21.76
·
Evaporation heat (kJ/mol): ~470
·
Debye temperature (K): 230.00
·
Pauling negativity number: 2.28
·
First ionizing energy (kJ/mol): 868.1
·
Oxidation states: 4, 2, 0
·
Lattice structure: Face-Centered Cubic
·
Lattice constant (Å): 3.920
Anne
Marie Helmenstine, Ph.D.
Introduction
Ph.D. in
biomedical sciences from the University of Tennessee at Knoxville - Oak Ridge
National Laboratory.
Science
educator with experience teaching chemistry, biology, astronomy, and
physics at the high school, college, and graduate levels.
ThoughtCo
and About Education chemistry expert since 2001.
Widely-published
graphic artist, responsible for printable periodic tables and other
illustrations used in science.
Experience
Anne
Helmenstine, Ph.D. has covered chemistry for ThoughtCo and About Education
since 2001, and other sciences since 2013. She taught chemistry, biology,
astronomy, and physics at the high school, college, and graduate levels.
She has worked as a research scientist and also abstracting and indexing
diverse scientific literature for the Department of Energy.
In
addition to her work as a science writer, Dr. Helmenstine currently serves as a
scientific consultant, specializing in problems requiring an interdisciplinary
approach. Previously, she worked as a research scientist and college
professor.
Education
Dr.
Helmenstine holds a Ph.D. in biomedical sciences from the University of
Tennessee at Knoxville and a B.A. in physics and mathematics with a minor
in chemistry from Hastings College. In her doctoral work, Dr. Helmenstine
developed ultra-sensitive chemical detection and medical diagnostic tests.
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