Showing posts with label Diamond. Show all posts
Showing posts with label Diamond. Show all posts

Tuesday, September 1, 2020

WHY GRAPHITE IS SOFT BUT DIAMOND IS SO HARD - Diamond and graphite are two allotropes of the same element (carbon) and the differences in their properties are a result of the way their crystal structures are arranged. Both diamond and graphite are made of pure carbon, yet they have dramatic differences in their properties. As allotropes of the same element, you might expect them to share many similarities, but that simply isn’t the case. Allotropy (also referred to as ‘allotropism’) of an element is that element’s ability to exist in multiple forms in the same physical state with a different arrangement of its atoms. The different forms are called allotropes of the given chemical element. Allotropes of the same element have different bonding arrangements, which give rise to different chemical and physical properties for the substance. Furthermore, different allotropes can also differ in the occurrence of molecules in the number of atoms. Carbon has the ability to form many allotropes, thanks to its chemical structure. Its atomic number is 6, which means that it has 4 electrons in its valence shell. No less than 8 allotropes of carbon have been identified. Out of all the known allotropes, the most popular ones are diamond and graphite. Although their composition is the same, they exhibit different chemical and physical properties, thanks to the arrangement of carbon atoms within them. It boils down to a single factor: geometry. The arrangement of carbon atoms in diamond follows a tetrahedral fashion. This means that each carbon atom is attached to 4 other carbon atoms, forming strong covalent bonds.

graphite-structure
............................................................................................................................................................
Carbon-atomWhy Is Graphite Soft, But Diamond Is So Hard?
By Ashish


Diamond and graphite are two allotropes of the same element (carbon) and the differences in their properties are a result of the way their crystal structures are arranged.
Both diamond and graphite are made of pure carbon, yet they have dramatic differences in their properties.
As allotropes of the same element, you might expect them to share many similarities, but that simply isn’t the case.
At first, this question might seem odd to many people. Diamond and graphite… doesn’t sound like a particularly sensible combination.
Diamond and gold, or diamond and sapphire would make more sense, right?
So, why is diamond pitted in the same category with graphite – the thing that we find inside our pencils?
Well, if you had paid attention to your Chemistry lessons in high school, you would know that there is, in fact, a very strong structural connection between the two.
What’s the connection between the two? And why are they so different from each other?
What are allotropes?
Allotropy (also referred to as ‘allotropism’) of an element is that element’s ability to exist in multiple forms in the same physical state with a different arrangement of its atoms.
The different forms are called allotropes of the given chemical element.
Triangle Rectangle & square shapes 36 ball
Triangle Rectangle & square shapes 36 ball
Imagine that you have 36 balls that you can arrange in any number of patterns to obtain mutually-visually geometrical shapes.
The constituent pieces of these shapes (balls) represent atoms, and the different shapes they assume (due to their varied arrangements) are the allotropes.
Allotropes of the same element have different bonding arrangements, which give rise to different chemical and physical properties for the substance.
Allotropes of Phosphorus & Allotropes of Oxygen
Allotropes of Phosphorus & Allotropes of Oxygen
Furthermore, different allotropes can also differ in the occurrence of molecules in the number of atoms.
The following image features various allotropes of phosphorus and oxygen.
Allotropes of carbon
Carbon-atomIn the world of allotropes, the carbon is nothing less than a rockstar. It has the ability to form many allotropes, thanks to its chemical structure.
Its atomic number is 6, which means that it has 4 electrons in its valence shell.
Eight allotropes of carbon
Different allotropes of carbon
As of now, no less than 8 allotropes of carbon have been identified, and the research for discovering even more allotropes is on.
However, out of all the known allotropes, the most popular ones are diamond and graphite.
These two allotropes, which visually appear incredibly different, are still made of nothing but carbon.
Although their composition is the same, they exhibit different chemical and physical properties, thanks to the arrangement of carbon atoms within them.
Why is diamond hard, but graphite is soft, despite being composed of the same element (carbon)?
It boils down to a single factor: geometry.
Diamond Structure
Diamond Structure
The arrangement of carbon atoms in diamond follows a tetrahedral fashion. This means that each carbon atom is attached to 4 other carbon atoms, forming strong covalent bonds.
This crystal arrangement is energetically very favorable and imparts that characteristic strength, durability and rigidity to diamond.
To scratch or break it requires a high amount of force, which makes it one of the hardest naturally-occurring materials on the planet.
Graphite, on the other hand, has an entirely different geometric arrangement than diamond.
Its carbon atoms are arranged in 2D sheets, whereas each carbon atom is bonded to three other carbon atoms to form hexagonal rings in an infinite array.
graphite-structure
graphite-structure
Although the bonding of atoms within each individual layer is covalent and therefore quite strong (as strong as is seen in diamond), the bonding between layers is weak (Van der Waals forces).
The result of this is that the layers slide over each and can detach from each other very easily.
These weak bonds between the multiple sheets of carbon atoms make the graphite used in pencils flake off on paper, allowing you to write.
In addition to being soft and slippery, graphite also has a much lower density than diamond.
The one thing about all of this that amazes me most is how a few tweaks in the chemical structure of identical substances make them so massively different in their appearance, toughness and chemical properties!

Ashish is a Science graduate (Bachelor of Science) from Punjabi University (India). He spends a lot of time watching movies, and an awful lot more time discussing them. He likes Harry Potter and the Avengers, and obsesses over how thoroughly Science dictates every aspect of life… in this universe, at least.

Sunday, September 22, 2019

COAL – the Organic Rock - Coal is made up of organic components; specifically, plant matter that has been buried in an anoxic, or non-oxygenated, environment and compressed over millions of years. Because it is organic, coal defies the normal standards of classification for rocks, minerals, and fossils. Coal differs from every other kind of rock in that it is made of organic carbon: the actual remains, not just mineralized fossils, of dead plants. The carbon in coal was preserved from oxidation and remains in a chemically reduced form, available for oxidation.

Coal
........................................................................................................................................................
Coal
the organic rock
Everything You Need to Know About Coal
by Andrew Alden 



Coal is an enormously valuable fossil fuel that has been used for hundreds of years in industry.
It is made up of organic components; specifically, plant matter that has been buried in an anoxic, or non-oxygenated, environment and compressed over millions of years. 
Fossil, Mineral or Rock?
Because it is organic, coal defies the normal standards of classification for rocks, minerals, and fossils: 
·           A fossil is any evidence of life that has been preserved in rock. The plant remains that make up coal have been "pressure cooked" for millions of years. Therefore, it is not accurate to say that they have been preserved. 
·          Minerals are inorganic, naturally-occurring solids. While coal is a naturally-occurring solid, it is composed of organic plant material.
·          Rocks are, of course, made up of minerals. 
Talk to a geologist, though, and they'll tell you that coal is an organic sedimentary rock.
Even though it doesn't technically meet the criteria, it looks like a rock, feels like a rock and is found between sheets of (sedimentary) rock. So, in this case, it is a rock. 
Geology isn't like chemistry or physics with their steadfast and consistent rules. It is an Earth science; and like the Earth, geology is full of "exceptions to the rule." 
State legislators struggle with this topic as well: Utah and West Virginia list coal as their official state rock while Kentucky named coal its state mineral in 1998. 
Coal: the Organic Rock
Coal differs from every other kind of rock in that it is made of organic carbon: the actual remains, not just mineralized fossils, of dead plants.
Today, the vast majority of dead plant matter is consumed by fire and decay, returning its carbon to the atmosphere as the gas carbon dioxide.
In other words, it is oxidized. The carbon in coal, however, was preserved from oxidation and remains in a chemically reduced form, available for oxidation.
Coal geologists study their subject the same way that other geologists study other rocks.
But instead of talking about the minerals that make up the rock (because there are none, just bits of organic matter), coal geologists refer to the components of coal as macerals.
There are three groups of macerals: inertinite, liptinite, and vitrinite.
To oversimplify a complex subject, inertinite is generally derived from plant tissues, liptinite from pollen and resins, and vitrinite from humus or broken-down plant matter.
Where Coal Formed
The old saying in geology is that the present is the key to the past.
Today, we can find plant matter being preserved in anoxic places: peat bogs like those of Ireland or wetlands like the Everglades of Florida.
And sure enough, fossil leaves and wood are found in some coal beds.
Therefore, geologists have long assumed that coal is a form of peat created by the heat and pressure of deep burial.
The geologic process of turning peat into coal is called "coalification."
Coal beds are much, much larger than peat bogs, some of them tens of meters in thickness, and they occur all over the world.
This says that the ancient world must have had enormous and long-lived anoxic wetlands when the coal was being made. 
Geologic History of Coal
While coal has been reported in rocks as old as Proterozoic (possibly 2 billion years) and as young as Pliocene (2 million years old), the great majority of the world's coal was laid down during the Carboniferous Period, a 60-million-year stretch (359-299 m.y.a.) when sea level was high and forests of tall ferns and cycads grew in gigantic tropical swamps.
The key to preserving the forests' dead matter was burying it.
We can tell what happened from the rocks that enclose the coal beds: there are limestones and shales on top, laid down in shallow seas, and sandstones beneath laid down by river deltas.
Obviously, the coal swamps were flooded by advances of the sea. This allowed shale and limestone to be deposited on top of them.
The fossils in the shale and limestone change from shallow-water organisms to deep-water species, then back to shallow forms.
Then sandstones appear as river deltas advance into the shallow seas and another coal bed is laid down on top. This cycle of rock types is called a cyclothem.
Hundreds of cyclothems occur in the rock sequence of the Carboniferous. Only one cause can do that - a long series of ice ages raising and lowering the sea level.
And sure enough, in the region that was at the south pole during that time, the rock record shows abundant evidence of glaciers.
That set of circumstances has never recurred, and the coals of the Carboniferous (and the following Permian Period) are the undisputed champions of their type.
It has been argued that about 300 million years ago, some fungus species evolved the ability to digest wood, and that was the end of the great age of coal, although younger coal beds do exist.
A genome study in Science gave that theory more support in 2012. If the wood was immune to rot before 300 million years ago, then perhaps anoxic conditions were not always necessary.
Grades of Coal
Coal comes in three main types or grades. First, the swampy peat is squeezed and heated to form a brown, soft coal called lignite.
In the process, the material releases hydrocarbons, which migrate away and eventually become petroleum.
With more heat and pressure lignite releases more hydrocarbons and becomes the higher-grade bituminous coal.
Bituminous coal is black, hard and usually dull to glossy in appearance.
Still greater heat and pressure yields anthracite, the highest grade of coal. In the process, the coal releases methane or natural gas.
Anthracite, a shiny, hard black stone, is nearly pure carbon and burns with great heat and little smoke. 
If coal is subjected to still more heat and pressure, it becomes a metamorphic rock as the macerals finally crystallize into a true mineral, graphite.
This slippery mineral still burns, but it is much more useful as a lubricant, an ingredient in pencils and other roles.
Still more valuable is the fate of deeply buried carbon, which at conditions found in the mantle is transformed into a new crystalline form: diamond.
However, coal probably oxidizes long before it can get into the mantle, so only Superman could perform that trick.
Andrew Alden
Professional geologist, writer, photographer, and geological tour guide
Thirty-seven years of experience writing about geological subjects
Six years as a research guide with U.S. Geological Survey (USGS)
Experience
Andrew Alden is a former writer for ThoughtCo who contributed hundreds of articles for more than 17 years. Andrew works as a geologist, writer, editor, and photographer. He has written on geological subjects since 1981 and participates actively in his field. For example, Andrew spent six years as a research guide with the U.S. Geological Survey, leading excursions on both land land and at sea. And since 1992, he has hosted the earthquakes conference for the online discussion platform, The Well, which began as a dialogue between the writers and readers of the Whole Earth Review. 
In addition, Andrew is a longtime member of the member of the Geological Society of America — an international society that serves members in academia, government, and industry; and the American Geophysical Union — a community of earth and space scientists that advances the power of science to ensure a sustainable future.
Andrew lives in Oakland, California; and though he writes about the whole planet and beyond, Andrew finds his own city full of interest too and blogs about its geology
Education
Andrew Alden holds a bachelor's (B.A.) degree in Earth Science from the University of New Hampshire, College of Engineering and Physical Sciences, in Durham, N.H.
Awards and Publications
Andrew Alden on Earthquakes (The Well Group, Inc., 2011)
Assessment of River — Floodplain Aquifer Interactions (Environmental and Engineering Geoscience, 1997)
Andrew Alden on Hosting (The Well Group, Inc., 1995)
ThoughtCo and Dotdash
ThoughtCo is a premier reference site focusing on expert-created education content. We are one of the top-10 information sites in the world as rated by comScore, a leading Internet measurement company. Every month, more than 13 million readers seek answers to their questions on ThoughtCo.
For more than 20 years, Dotdash brands have been helping people find answers, solve problems, and get inspired. We are one of the top-20 largest content publishers on the Internet according to comScore, and reach more than 30% of the U.S. population monthly. Our brands collectively have won more than 20 industry awards in the last year alone, and recently Dotdash was named Publisher of the Year by Digiday, a leading industry publication.
Coal

Friday, January 26, 2018

GRAPHENE - Carbon is very special. It can form diamond and graphite—even though the former is super hard and the latter is quite soft. Graphene is another form of carbon material - this time a single layer of graphite. It has very useful electrical, thermal, and physical properties. Its applications include replacing silicon in areas like electronic devices.

 
.
Graphene
Seeing God’s Handiwork and Care in Chemistry
by Avery Foley 


God’s creation is filled with amazing design.
Often when we think of design, we immediately picture hummingbirds, butterflies, or the human body.
But God’s design can be seen in the obvious and the not so obvious.
Have you ever stopped to consider how even chemistry showcases God’s handiwork, creativity, and care for his creation?

Graphene, the “Wonder Material”

Carbon, the sixth element on the periodic table, is considered “King of the Elements.”
It appears in three major forms in nature. One of these forms, diamond, is transparent and the hardest known material while another form, graphite, is black and very soft.
Carbon is essential to life.
In 2002 researchers at the University of Manchester isolated graphene, an ultra-thin sheet of carbon atoms, by peeling off layers of graphite with tape until they had a layer just one atom thick.
Now the strongest material known to man, this “wonder material” is pliable, strong, and conductive.
Professor Stuart Burgess, a professor and gifted design engineer at the University of Bristol in the UK (and a biblical creationist), says this of carbon and graphene,
Carbon is very special. It can form diamond and graphite—even though the former is super hard and the latter is quite soft.
Graphene is another form of carbon material - this time a single layer of graphite.
It has very useful electrical, thermal, and physical properties. Its applications include replacing silicon in areas like electronic devices.
It is truly remarkable how God can design carbon to do such diverse things by simply changing the type of bond connections in the structure!
Some of the things we see as simple in creation—like water (H2O) and carbon (C) - are actually profound Designer materials [materials that bear hallmarks of having been formed for a purpose by a Designer] that have remarkable properties that are useful to man.

Graphene and Seawater

Providing clean water to those around the world is a challenge many engineers are seeking to solve.
Theoretically the oceans are an endless source of water—except, of course, for the problem that it’s not drinkable.
But researchers in the UK recently announced that they’ve developed a sieve using a compound called graphene oxide to filter seawater.
Previous attempts have been unsuccessful because the graphene oxide swelled in the water, allowing particles to go through.
But researchers now say they can control the size and expansion of the pores by using an epoxy resin coat over the graphene oxide membrane.
This allows salt, and other impurities, to be filtered out, leaving fresh drinking water.
While this energy-efficient method still needs further research and development before it can be used, it’s an exciting prospect that will perhaps allow millions to access fresh water.

God’s Care for Creation

God’s design and care for his creation can be seen everywhere we look.
The more we study what he has made, the more we realize that he has put his fingerprints on everything from small molecules to blue whales.
Our world truly is a designer world. It should cause us to say, along with the psalmist,
When I look at your heavens, the work of your fingers, the moon and the stars, which you have set in place, what is man that you are mindful of him, and the son of man that you care for him? (Psalm 8:3–4)

Avery Foley is a writer for Answers in Genesis from Ontario, Canada. She holds a masters of arts in theological studies from Liberty Baptist Theological Seminary.
.
Multi-Media Filter, Highly-Activated Carbon Filter,
Zeolite-Process Water Softener With Brine Tank,
Fiberglass Ballast-Type Pressure Tank
(fully automatic backwash & regeneration)
.
PURICARE 
INDUSTRIAL 
ENTERPRISES 
Water 
Treatment 
Systems
.
.
...
Aganan, Pavia, Iloilo, Philippines
...
CLICK HERE . . . to view company profile . . .

Tachmina Laminated
Sand Filter


Reverse Osmosis with Cartridge Pre-Filters
Ultraviolet Bactericidal System
with Cartridge Pre-Filters











...