SOURCES OF CFCS - Chlorofluorocarbons, also known as CFCs, consist of chemical compounds made up of chlorine, fluorine and carbon. CFCs are particularly harmful when released into the atmosphere because of their destructive reaction with O-zone particles, which provide the Earth with a protective layer against UV radiation. A few specialized products still contain CFCs. The most common source of CFCs are refrigerants, but fire suppression systems for aircraft and aerosols also emit CFCs into the atmosphere. Dupont brand named their new product “Freon” and various other brand names produced the CFC-based refrigerant worldwide. When the coolant used in old refrigerators, cars, air conditioners and other machines is not properly disposed of, it leaks CFCs into the atmosphere as liquids evaporate or work their way into the soil. Aviation regulations in some countries still require fire suppression systems outfitted with Halon, a coolant containing CFCs. There is no safe, effective alternative. The industry must follow certain safety measures to dispose of this dangerous chemical responsibly and to recycle the material when possible. Aerosol cans and propellant liquids used gasses containing CFCs for a long time. They were phased out of aerosol production in 1999 in favor of less harmful hydrocarbon alternatives. However, since CFC molecules have a lifetime of 20 to 100 years in the stratosphere, the damage done in previous decades continues to make an impact. As refrigerants and aerosol cans containing CFCs become older and more obsolete, people tend to forget about them, leaving them to leak and further contaminate the atmosphere.

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Sources of CFCs

What Are the Sources of CFCs?

By Tommy Doc

 

Chlorofluorocarbons, also known as CFCs, consist of chemical compounds made up of chlorine, fluorine and carbon.

CFCs are particularly harmful when released into the atmosphere because of their destructive reaction with O-zone particles, which provide the Earth with a protective layer against UV radiation.

Since 1995 most countries have virtually eliminated CFC production, but a few specialized products still contain CFCs.

TL; DR (Too Long; Didn't Read)

The most common source of CFCs are refrigerants, but fire suppression systems for aircraft and aerosols also emit CFCs into the atmosphere.

Refrigerators and Air Conditioners

The most common emitter of CFCs are refrigerants, particularly those used after the 1930s.

Dupont brand named their new product “Freon” and various other brand names produced the CFC-based refrigerant worldwide.

When the coolant used in old refrigerators, cars, air conditioners and other machines is not properly disposed of, it leaks CFCs into the atmosphere as liquids evaporate or work their way into the soil.

Aircraft Halon

Aviation regulations in some countries still require fire suppression systems outfitted with Halon, a coolant containing CFCs.

As of 2011, there is no safe, effective alternative. The industry must follow certain safety measures to dispose of the this dangerous chemical responsibly and to recycle the material when possible.

Aerosol Sprays

Aerosol cans and propellant liquids used gasses containing CFCs for a long time.

They were phased out of aerosol production in 1999 in favor of less harmful hydrocarbon alternatives.

However, since CFC molecules have a lifetime of 20 to 100 years in the stratosphere, the damage done in previous decades continues to make an impact.

Rogue CFCs

As refrigerants and aerosol cans containing CFCs become older and more obsolete, people tend to forget about them, leaving them to leak and further contaminate the atmosphere.

Researchers at the University of East Anglia are working on methods to pinpoint local sources of CFC exposure, such as old CFC refrigerators.

They collect air from the stratosphere and use mass spectrometers to determine the chemical makeup of CFC contamination.

Tommy Doc is a 2007 graduate of the University of Pennsylvania and an aspiring Internet entrepreneur. He was the sports editor for "The Pennsylvania Independent" while attaining his bachelor's degree in communications and environmental science. Doc is from Atlantic City, N.J. but has lived in Philadelphia, San Diego, New York and currently resides in Austin, Texas.

https://sciencing.com/sources-cfcs-8405334.html

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CRYOGENICS – It is used to produce cryogenic fuels for rockets, including liquid hydrogen and liquid oxygen (LOX). The strong electromagnetic fields needed for nuclear magnetic resonance (NMR) are usually produced by supercooling electromagnets with cryogens. Magnetic resonance imaging (MRI) is an application of NMR that uses liquid helium. Infrared cameras frequently require cryogenic cooling. Cryogenic freezing is used to transport or store large quantities of food. Liquid nitrogen is used to produce fog for special effects and even specialty cocktails and food. Freezing materials using cryogens can make them brittle enough to be broken into small pieces for recycling. Cryogenic temperatures are used to store tissue and blood specimens and to preserve experimental samples. Cryogenic cooling of superconductors may be used to increase electric power transmission for big cities. Cryogenic processing is used as part of some alloy treatments and to facilitate low temperature chemical reactions.

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Cryogenics

Understanding the Concept of Cryogenics

What Cryogenics Is and How It's Used

by Anne Marie Helmenstine, Ph.D. 

Cryogenics is defined as the scientific study of materials and their behavior at extremely low temperatures.

The word comes from the Greek cryo, which means "cold", and genic, which means "producing".

The term is usually encountered in the context of physics, materials science, and medicine.

A scientists who studies cryogenics is called a cryogenicist.

A cryogenic material may be termed a cryogen.

Although cold temperatures may be reported using any temperature scale, the Kelvin and Rankine scales are most common because they are absolute scales that have positive numbers.

Exactly how cold a substance has to be to be considered "cryogenic" is a matter of some debate by the scientific community.

The U.S. National Institute of Standards and Technology (NIST) considers cryogenics to include temperatures below −180 °C (93.15 K; −292.00 °F), which is a temperature above which common refrigerants (e.g., hydrogen sulfide, freon) are gases and below which "permanent gases" (e.g., air, nitrogen, oxygen, neon, hydrogen, helium) are liquids.

There is also a field of study called "high temperature cryogenics", which involves temperatures above the boiling point of liquid nitrogen at ordinary pressure (−195.79 °C (77.36 K; −320.42 °F), up to −50 °C (223.15 K; −58.00 °F).

Measuring the temperature of cryogens requires special sensors.

Resistance temperature detectors (RTDs) are used to take temperature measurements as low as 30 K. Below 30 K, silicon diodes are often used.

Cryogenic particle detectors are sensors that operate a few degrees above absolute zero and are used to detect photons and elementary particles.

Cryogenic liquids are typically stored in devices called Dewar flasks. These are double-walled containers that have a vacuum between the walls for insulation.

Dewar flasks intended for use with extremely cold liquids (e.g., liquid helium) have an additional insulating container filled with liquid nitrogen.

Dewar flasks are named for their inventor, James Dewar.

The flasks allow gas to escape the container to prevent pressure buildup from boiling that could lead to an explosion.

Cryogenic Fluids

The following fluids are most often used in cryogenics:

Fluid	Boiling Point (K)
Helium-3	3.19
Helium-4	4.214
Hydrogen	20.27
Neon	27.09
Nitrogen	77.36
Air	78.8
Fluorine	85.24
Argon	87.24
Oxygen	90.18
Methane	111.7

Uses of Cryogenics

There are several applications of cryogenics. It is used to produce cryogenic fuels for rockets, including liquid hydrogen and liquid oxygen (LOX).

The strong electromagnetic fields needed for nuclear magnetic resonance (NMR) are usually produced by supercooling electromagnets with cryogens.

Magnetic resonance imaging (MRI) is an application of NMR that uses liquid helium. 

Infrared cameras frequently require cryogenic cooling.

Cryogenic freezing of food is used to transport or store large quantities of food.

Liquid nitrogen is used to produce fog for special effects and even specialty cocktails and food.

Freezing materials using cryogens can make them brittle enough to be broken into small pieces for recycling.

Cryogenic temperatures are used to store tissue and blood specimens and to preserve experimental samples.

Cryogenic cooling of superconductors may be used to increase electric power transmission for big cities.

Cryogenic processing is used as part of some alloy treatments and to facilitate low temperature chemical reactions (e.g., to make statin drugs). 

Cryomilling is used to mill materials that may be too soft or elastic to be milled at ordinary temperatures.

Cooling of molecules (down to hundreds of nano Kelvins) may be used to form exotic states of matter. The Cold Atom Laboratory (CAL) is an instrument designed for use in microgravity to form Bose Einstein condensates (around 1 pico Kelvin temperature) and test laws of quantum mechanics and other physics principles.

Cryogenic Disciplines

Cryogenics is a broad field that encompasses several disciplines, including:

Cryonics - Cryonics is the cryopreservation of animals and humans with the goal of reviving them in the future.

Cryosurgery - This is a branch of surgery in which cryogenic temperatures are used to kill unwanted or malignant tissues, such as cancer cells or moles.

Cryoelectronics - This is the study of superconductivity, variable-range hopping, and other electronic phenomena at low temperature. The practical application of cryoelectronics is called cryotronics.

Cryobiology - This is the study of the effects of low temperatures on organisms, including the preservation of organisms, tissue, and genetic material using cryopreservation.

Cryogenics Fun Fact

While cryogenics usually involves temperature below the freezing point of liquid nitrogen yet above that of absolute zero, researchers have achieved temperatures below absolute zero (so-called negative Kelvin temperatures).

In 2013 Ulrich Schneider at the University of Munich (Germany) cooled gas below absolute zero, which reportedly made it hotter instead of colder!

Anne Marie Helmenstine, Ph.D.

Introduction

Ph.D. in biomedical sciences from the University of Tennessee at Knoxville - Oak Ridge National Laboratory.

Science educator with experience teaching chemistry, biology, astronomy, and physics at the high school, college, and graduate levels.

ThoughtCo and About Education chemistry expert since 2001.

Widely-published graphic artist, responsible for printable periodic tables and other illustrations used in science.

Experience

Anne Helmenstine, Ph.D. has covered chemistry for ThoughtCo and About Education since 2001, and other sciences since 2013. She taught chemistry, biology, astronomy, and physics at the high school, college, and graduate levels. She has worked as a research scientist and also abstracting and indexing diverse scientific literature for the Department of Energy.

In addition to her work as a science writer, Dr. Helmenstine currently serves as a scientific consultant, specializing in problems requiring an interdisciplinary approach. Previously, she worked as a research scientist and college professor. 

Education

Dr. Helmenstine holds a Ph.D. in biomedical sciences from the University of Tennessee at Knoxville and a B.A. in physics and mathematics with a minor in chemistry from Hastings College. In her doctoral work, Dr. Helmenstine developed ultra-sensitive chemical detection and medical diagnostic tests.

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https://www.thoughtco.com/cryogenics-definition-4142815