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Foam Definition in Chemistry
What Is Foam in Chemistry Terms?
by Anne Marie
Helmenstine, Ph.D.
A foam is a substance made by trapping air or gas bubbles
inside a solid or liquid.
Typically, the volume of gas is much larger than that of
the liquid or solid, with thin films separating gas pockets.
Another definition of foam is a bubbly liquid,
particularly if the bubbles,
or froth, are undesirable.
Foam can impede the flow of a liquid and block gas
exchange with air. Anti-foaming agents may be added to a liquid to help prevent
bubbles from forming.
The term foam may also refer to other phenomena that
resemble foams, such as foam rubber and quantum foam.
How Foam Forms
Three requirements must be met in order for foam to form.
Mechanical work is needed to increase the surface area.
This can occur by agitation, dispersing a large volume of
gas into a liquid, or injecting a gas into a liquid.
The second requirement is that surfactants or
surface active components must be present to decrease surface tension.
Finally, the foam must form more quickly than it breaks
down.
Foams may be open-cell or closed-cell in nature. Pores
connect the gas regions in open-cell foams, while closed-cell foams have
enclosed cells.
The cells are usually disordered in their arrangement,
with varying bubble sizes. The cells present minimal surface area, forming
honeycomb shapes or tessellations.
Foams are stabilized by the Marangoni effect and by van der Waals
forces.
The Marangoni effect is a mass transfer along the
interface between fluids due to surface tension gradient.
In foams, the effect acts to restore lamellae (a network
of interconnected films).
Van der Waals forces form electric double layers when
dipolar surfactants are present.
Foams are destabilized as gas bubbles rise through them.
Also, gravity pulls liquid downward in a liquid-gas foam.
Osmotic pressure drains lamellae because of concentration
differences throughout the structure. Laplace pressure and disjoining pressure
also act to destabilize foams.
Examples of Foam
Examples of foams formed by gases in liquids include
whipped cream, fire retardant foam, and soap bubbles.
Rising bread dough may be considered a semisolid foam.
Solid foams include dry wood, polystyrene foam, memory foam, and mat foam (as
for camping and yoga mats). It's also possible to make a foam using metal.
Foam Uses
Bubbles and bath foam are fun uses of foam, but it has
many practical uses, too.
· Fire retardant foam is used to
extinguish fires.
· Solid foams may be used to engineer
strong yet light materials.
· Solid foams are excellent thermal
insulators.
· Solid foams are used to make
flotation devices.
· Because solid foams are light and
compressible, they make an excellent stuffing and packing material.
· A closed-cell foam called a syntactic
foam consists of hollow particles in a matrix. This type of foam is used to
make shape memory resins. Syntactic foams are also used in space and deep-sea
exploration.
· Self-skin or integral skin foam
consists of a dense skin with a lower density core. This type of foam is used
to make shoe soles, mattresses, and baby seats.
Anne Marie Helmenstine, Ph.D.
Introduction
Ph.D. in biomedical sciences from the University of
Tennessee at Knoxville - Oak Ridge National Laboratory.
Science educator with experience teaching chemistry,
biology, astronomy, and physics at the high school, college, and graduate
levels.
ThoughtCo and About Education chemistry expert since 2001.
Widely-published graphic artist, responsible for printable
periodic tables and other illustrations used in science.
Experience
Anne Helmenstine, Ph.D. has covered chemistry for
ThoughtCo and About Education since 2001, and other sciences since 2013. She
taught chemistry, biology, astronomy, and physics at the high school, college,
and graduate levels. She has worked as a research scientist and also
abstracting and indexing diverse scientific literature for the Department of
Energy.
In addition to her work as a science writer, Dr.
Helmenstine currently serves as a scientific consultant, specializing in
problems requiring an interdisciplinary approach. Previously, she worked
as a research scientist and college professor.
Education
Dr. Helmenstine holds a Ph.D. in biomedical sciences from
the University of Tennessee at Knoxville and a B.A. in physics and
mathematics with a minor in chemistry from Hastings College. In her
doctoral work, Dr. Helmenstine developed ultra-sensitive chemical detection and
medical diagnostic tests.
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