COMPOSITION OF FIRE - Is Fire a Gas, Liquid, or Solid? - Fire is made up of many different substances, so it is not an element. The modern definition of an element relates to the number of protons a pure substance possesses. Mostly, fire is a mixture of hot gases. Flames are the result of a chemical reaction, primarily between oxygen in the air and a fuel. In addition to other products, the reaction produces carbon dioxide, steam, light, and heat. If the flame is hot enough, the gases are ionized and become yet another state of matter: plasma. Burning a metal, can ionize the atoms and form plasma. This type of oxidation is the source of the intense light and heat of a plasma torch. While there is a small amount of ionization going on in an ordinary fire, most of the matter in the flame is a gas. Thus, the safest answer for "What is the state of matter of fire?" is to say it's a gas. Or, you can say it's mostly gas, with a smaller amount of plasma.

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Composition Of Fire

Is Fire a Gas, Liquid, or Solid?

by Anne Marie Helmenstine, Ph.D.

The ancient Greeks and alchemists thought that fire was itself an element, along with earth, air, and water.

However, the modern definition of an element relates to the number of protons a pure substance possesses.

Fire is made up of many different substances, so it is not an element.

For the most part, fire is a mixture of hot gases.

Flames are the result of a chemical reaction, primarily between oxygen in the air and a fuel, such as wood or propane.

In addition to other products, the reaction produces carbon dioxide, steam, light, and heat.

If the flame is hot enough, the gases are ionized and become yet another state of matter: plasma.

Burning a metal, such as magnesium, can ionize the atoms and form plasma. This type of oxidation is the source of the intense light and heat of a plasma torch.

While there is a small amount of ionization going on in an ordinary fire, most of the matter in the flame is a gas.

Thus, the safest answer for "What is the state of matter of fire?" is to say it's a gas.

Or, you can say it's mostly gas, with a smaller amount of plasma.

Different Parts of a Flame

There are several parts of a flame; each is made up of different chemicals.

Near the base of a flame, oxygen, and fuel vapor mix as unburned gas. The composition of this part of the flame depends on the fuel that is being used.

Above this is the region where the molecules react with each other in the combustion reaction. Again, the reactants and products depend on the nature of the fuel.

Above this region, combustion is complete, and the products of the chemical reaction may be found.

Typically, these are water vapor and carbon dioxide. If combustion is incomplete, a fire may also give off tiny solid particles of soot or ash.

Additional gases may be released from incomplete combustion, especially of "dirty" fuel, such as carbon monoxide or sulfur dioxide.

While it's difficult to see it, flames expand outward like other gases. In part, this is hard to observe because we only see the portion of the flame that is hot enough to emit light.

A flame isn't round (except in space) because the hot gases are less dense than the surrounding air, so they rise up.

The color of the flame is an indication of its temperature and the chemical composition of the fuel.

A flame emits incandescent light, which means that light with the highest energy (the hottest part of the flame) is blue, and that with the least energy (the coolest part of the flame) is redder.

The chemistry of the fuel plays its part as well, and this is the basis for the flame test to identify chemical composition. For example, a blue flame may appear green if a boron-containing salt is present.

Anne Marie Helmenstine, Ph.D.

Introduction

Ph.D. in biomedical sciences from the University of Tennessee at Knoxville - Oak Ridge National Laboratory.

Science educator with experience teaching chemistry, biology, astronomy, and physics at the high school, college, and graduate levels.

ThoughtCo and About Education chemistry expert since 2001.

Widely-published graphic artist, responsible for printable periodic tables and other illustrations used in science.

Experience

Anne Helmenstine, Ph.D. has covered chemistry for ThoughtCo and About Education since 2001, and other sciences since 2013. She taught chemistry, biology, astronomy, and physics at the high school, college, and graduate levels. She has worked as a research scientist and also abstracting and indexing diverse scientific literature for the Department of Energy.

In addition to her work as a science writer, Dr. Helmenstine currently serves as a scientific consultant, specializing in problems requiring an interdisciplinary approach. Previously, she worked as a research scientist and college professor.

Education

Dr. Helmenstine holds a Ph.D. in biomedical sciences from the University of Tennessee at Knoxville and a B.A. in physics and mathematics with a minor in chemistry from Hastings College. In her doctoral work, Dr. Helmenstine developed ultra-sensitive chemical detection and medical diagnostic tests.

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https://www.thoughtco.com/what-state-of-matter-is-fire-604300