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Garnet
Best known as a red gemstone. It occurs in many colors and has numerous industrial uses.
Best known as a red gemstone. It occurs in many colors and has numerous industrial uses.
Author: Hobart
M. King, Ph.D.,
GIA Graduate Gemologist
What is Garnet?
Garnet
is the name used for a large group of rock-forming minerals.
These minerals share
a common crystal structure and a generalized chemical composition of X3Y2(SiO4)3.
In
that composition, "X" can be Ca, Mg, Fe2+ or Mn2+,
and "Y" can be Al, Fe3+, Mn3+, V3+ or
Cr3+.
These
minerals are found throughout the world in metamorphic, igneous, and sedimentary rocks.
Most
garnet found near Earth's surface forms when a sedimentary rock with a high
aluminum content, such as shale, is subjected to heat and pressure
intense enough to produce schist or gneiss.
Garnet
is also found in the rocks of contact metamorphism, subsurface magma chambers,
lava flows, deep-source volcanic eruptions, and the soils and sediments formed
when garnet-bearing rocks are weathered and eroded.
Most
people associate the word "garnet" with a red gemstone;
however, they are often surprised to learn that garnet occurs in many other
colors and has many other uses.
In
the United States, the major industrial uses of garnet in 2012 were waterjet
cutting (35%), abrasive blasting media (30%), water filtration granules (20%),
and abrasive powders (10%).
The Garnet Group: This chart
summarizes the members of the garnet group that are most important as
gemstones.
The aluminum garnets
are normally red in color with a higher specific gravity and hardness.
The calcium members are
usually green in color and have a lower hardness.
Physical
Properties of Garnet
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|
Chemical Classification
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Silicate
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Color
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Typically red, but can be orange, green,
yellow, purple, black, or brown. Blue garnets are extremely rare.
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Streak
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Colorless
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Luster
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Vitreous
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Diaphaneity
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Transparent to translucent
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Cleavage
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None
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Mohs Hardness
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6.5 to.5
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Specific Gravity
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3.5 to 4.3
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Diagnostic Properties
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Hardness, specific gravity, isometric
crystal form, lack of cleavage
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Chemical Composition
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General formula: X3Y2(SiO4)3
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Crystal System
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Isometric
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Uses
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Waterjet cutting granules, abrasive blasting
granules, filtration granules, abrasive grits and powders, gemstones
|
Garnet Physical and Chemical Properties
The
most commonly encountered minerals in the garnet group include almandine,
pyrope, spessartine, andradite, grossular, and uvarovite.
They
all have a vitreous luster, a transparent-to-translucent diaphaneity, a brittle
tenacity, and a lack of cleavage.
They
can be found as individual crystals, stream-worn pebbles, granular aggregates,
and massive occurrences.
Their
chemical composition, specific gravity, hardness, and colors are listed below.
Garnet
Minerals
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||||
Mineral
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Composition
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Specific Gravity
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Hardness
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Colors
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Almandine
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Fe3Al2(SiO4)3
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4.20
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7 - 7.5
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red, brown
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Pyrope
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Mg3Al2(SiO4)3
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3.56
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7 - 7.5
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red to purple
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Spessartine
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Mn3Al2(SiO4)3
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4.18
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6.5 - 7.5
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orange to red to brown
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Andradite
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Ca3Fe2(SiO4)3
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3.90
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6.5 - 7
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green, yellow, black
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Grossular
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Ca3Al2(SiO4)3
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3.57
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6.5 - 7.5
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green, yellow, red, pink, clear
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Uvarovite
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Ca3Cr2(SiO4)3
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3.85
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6.5 - 7
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green
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The compositions listed above are for end members of several
solid solution series.
There are a number of other garnet minerals that are less
frequently encountered and not as important in industrial use.
They include goldmanite, kimzeyite, morimotoite, schorlomite,
hydrogrossular, hibschite, katoite, knorringite, majorite, and calderite.
|
As seen above, there are a variety of
different types of garnet, and each has a different chemical composition.
There
are also solid solution series between most of the garnet minerals. This wide
variation in chemistry determines many of their physical properties.
As
an example, the calcium garnets generally have a lower specific gravity, a
lower hardness and are typically green in
color.
In
contrast, the iron and manganese garnets have a higher specific gravity, a
greater hardness and are typically red in color.
How Does Garnet Form?
Garnet
in Metamorphic Rocks
Most
garnet forms at convergent plate boundaries where shale is
being acted upon by regional metamorphism.
The
heat and pressure of metamorphism breaks chemical bonds and causes minerals to
recrystallize into structures that are stable under the new
temperature-pressure environment.
The
aluminum garnet, almandine, generally forms in this environment.
As
these rocks are metamorphosed, the garnets start as tiny grains and enlarge
slowly over time as metamorphism progresses.
.As
they grow, they displace, replace, and include the surrounding rock materials.
The photo below shows a microscopic view of a garnet grain that has grown
within a schist matrix.
It
included a number of the host rock's mineral grains as it grew. This explains
why so many garnets formed by regional metamorphism are highly included.
The
calcium garnets typically form when argillaceous limestone is
altered into marble by contact metamorphism along
the edges of igneous intrusions.
These
are andradite, grossular, and uvarovite, the slightly softer, typically green
garnets with a lower specific gravity.
Two
calcium garnets are highly regarded in the gem trade; they are tsavorite (a
bright green grossular) and demantoid (a golden-green andradite).
Garnet
in Igneous Rocks
Garnet
often occurs as an accessory mineral in igneous rocks such as granite.
Many
people are familiar with almandine garnet because it is sometimes seen as dark
red crystals in the igneous rocks used as granite countertops.
Spessartine
is an orange garnet found as crystals in granite
pegmatites.
Pyrope
is a red garnet that is brought to Earth's surface in pieces of peridotite that
were torn from the mantle during deep-source volcanic eruptions.
Garnet
is also found in basaltic lava flows.
Garnet
in Sedimentary Rocks and Sediments
Garnets
are relatively durable minerals. They are often found concentrated in the soils
and sediments that form when garnet-bearing rocks are weathered and eroded.
These
alluvial garnets are often the target of mining operations because they are
easy to mine and remove from the sediment/soil by mechanical processing.
Uses of Garnet: This chart shows
the most common industrial uses of garnet minerals. Almandine is the variety of
garnet that is most often used in industry.
Uses of Garnet
Garnet
has been used as a gemstone for thousands of years. In
the past 150 years, it has seen many additional uses as an industrial mineral.
The
chart below shows recent industrial uses of garnet in the United States.
Garnet
is also used as an indicator mineral during mineral exploration and geologic
assessments.
Garnet as an Industrial Mineral
Garnet
Abrasives
The
first industrial use of garnet was as an abrasive.
Garnet
is a relatively hard mineral with a hardness that ranges between 6.5 and 7.5 on
the Mohs Scale.
That
allows it to be used as an effective abrasive in many types of manufacturing.
When
crushed, it breaks into angular pieces that provide sharp edges for cutting and
sanding.
Small
granules of uniform size are bonded to paper to produce a reddish color
sandpaper that is widely used in woodworking shops.
Garnet
is also crushed, screened to specific sizes, and sold as abrasive granules and
powders.
In
the United States, New York and Idaho have been important sources of
industrial garnet for abrasives.
Waterjet
Cutting
The
largest industrial use of garnet in the United States is in waterjet cutting.
A
machine known as a waterjet cutter produces a high-pressure jet of water with
entrained abrasive granules.
When
these are directed at a piece of metal, ceramic, or stone, a cutting action can
occur that produces very little dust and cuts at a low temperature.
Waterjet
cutters are used in manufacturing and mining.
Abrasive
Blasting
Garnet
granules are also used in abrasive blasting (commonly known as "sand
blasting").
In
these processes, a tool propels a stream of abrasive granules (also known as
"media") against a surface using a highly pressurized fluid (usually
air or water) as a propellant.
Abrasive
blasting is done in order to smooth, clean, or remove oxidation products from
metals, brick, stone, and other materials.
It
is usually much faster than sanding by hand or with a sanding machine. It can
clean small and intricate surfaces that other cleaning methods would miss.
Abrasives
of various hardnesses can be used to clean a surface of greater hardness,
without damaging the surface.
Filtration
Garnet
granules are often used as a filter media. Small garnet particles are used to
fill a container through which a liquid flows.
The
pore spaces of the garnet are small enough to allow passage of the liquid but
are too small to allow passage of some contaminant particles, which are
filtered from the flow.
Garnet
is suited for this use because it is relatively inert and has a relatively high
specific gravity.
Garnet
granules, crushed and graded to about 0.3 millimeters in size, can be used to
filter out contaminant particles as small as a few microns in diameter.
Garnet's
high specific gravity and high hardness reduce bed expansion and particle
abrasion during backflushing.
Garnet as a Geological Indicator Mineral
Although
most of the garnets found at Earth's surface have formed within the crust, some
garnets are brought up from the mantle during deep-source volcanic eruptions.
These
eruptions entrain pieces of mantle rock known as "xenoliths" and
deliver them to the surface in a structure known as a "pipe."
These
xenoliths are the source of most diamonds found at or near Earth's
surface.
Although
xenoliths contain diamonds, they often contain a tremendous number of garnets
for every diamond, and those garnets are generally larger in size.
These
deep-source garnets are very different from the garnets that form in the crust
at shallow depth. So, a good way to prospect for diamonds is to look for these
unique garnets.
The
garnets serve as "indicator minerals" for geologists exploring for
diamond deposits. As the xenoliths weather, their garnets are liberated in
large numbers.
These
unusual garnets then move downslope in soils and streams. Geologists who find
them can follow the garnet trail to the source deposit.
Some
of the diamond pipes in Canada were found by
following a garnet trail produced by moving ice.
Garnets as Gemstones
Garnet
has been used as a gemstone for over 5000 years.
It
has been found in the jewelry of many Egyptian burials and was the most
popular gemstone of Ancient Rome.
It
is a beautiful gem that is usually sold without treatment of any kind. It is
also durable and common enough that it can be used in jewelry at a relatively
low cost.
Garnet
continues as a popular gemstone today. It serves as a birthstone for the month
of January and is a traditional gem given on a second anniversary.
Most
people will think of a red gemstone when they hear the name "garnet"
because they are not aware that garnet occurs in a variety of colors.
However,
gem-quality garnets occur in every color - with red being the most common and
blue garnets being especially rare.
Red
almandine is the red garnet most often found in jewelry because it is abundant
and inexpensive.
Pyrope
and spessartine are reddish garnets that are commonly encountered in jewelry
for the same reason.
In
recent decades, green demantoid garnet has become popular. It has a dispersion
of 0.057 that gives it a "fire" which exceeds that of diamond's at
0.044.
Green
tsavorite has a bright, rich color that is very much like emerald.
It is commonly used as an alternative stone to emerald.
Both
of these green garnets are becoming more popular, but their price is much
higher than almandine.
Hobart
M. King, Ph.D., GIA Graduate Gemologist
Gem garnets: Most people think that garnet is a red gemstone. However, garnet occurs in a wide variety of colors. Clockwise from the top left: red almandine (Madagascar), green tsavorite (Tanzania), yellow mali (Mali), orange spessartite (Mozambique), pink malaya (Tanzania), green merelani mint (Tanzania), red pyrope (Ivory Coast), green demantoid (Namibia), purple rhodolite (Mozambique), and orange hessonite (Sri Lanka). Seven out of eight of the garnets above are from Africa, the relatively new source of spectacular garnets.
The Garnet Group: This chart summarizes the members of the garnet group that are most important as gemstones. The aluminum garnets are normally red in color with a higher specific gravity and hardness. The calcium members are usually green in color and have a lower hardness.
Garnet mica schist in thin section: This is a microscopic view of a garnet grain that has grown in schist. The large black grain is the garnet, the red elongate grains are mica flakes. The black, gray, and white grains are mostly silt or smaller size grains of quartz and feldspar. The garnet has grown by replacing, displacing, and including the mineral grains of the surrounding rock. You can see many of these grains as inclusions within the garnet. From this photo it is easy to understand why clean, gem-quality garnets with no inclusions are very hard to find. It is also hard to understand how garnet can grow into nice euhedral crystals under these conditions. Photo by Jackdann88, used here under a Creative Commons license.
Garnet Sandpaper: Crushed garnet granules are used to make garnet sandpaper. Garnet serves as an excellent abrasive, especially for sanding wood. The crushed garnet granules are very sharp, and as the paper is used the granules fracture to expose new sharp surfaces. If you see sandpaper covered with reddish brown granules, look at the back to see if it is garnet paper.
Diamond pipe: Simplified cross-section of a diamond pipe and residual soil deposit showing the relationships of xenoliths and diamonds with the pipe and residual soil.
Almandine garnet: Excellent cubic crystals of almandine garnet in a fine-grained mica schist from Granatenkogel Mountain, Austria. Specimen and photo by Arkenstone / www.iRocks.com.
Andradite garnet: Green andradite garnet of the demantoid variety on a matrix of marble. This specimen is about 8.9 x 6.5 x 4.8 centimeters in size and was collected in Antsiranana Province, Madagascar. Garnets formed within marble often have excellent crystal form and are of very high quality. Specimen and photo by Arkenstone / www.iRocks.com.
Garnet gneiss: A coarse-grained gneiss composed mainly of hornblende (black), plagioclase (white) and garnet (red) from Norway. Public domain photo by Woudloper.
Alluvial garnet crystals: These almandine-spessartine garnets are from an alluvial deposit in Idaho. They have been transported a short distance from their source rock, and some still retain evidence of their dodecahedral crystal form. They are about four to five millimeters in size and weigh about 0.6 to 0.8 carats each.
Uses of Garnet: This chart shows the most common industrial uses of garnet minerals. Almandine is the variety of garnet that is most often used in industry.
Garnet abrasive: This photo shows garnet granules that have been crushed and size-graded for use as abrasive, cutting, and filter media. They are used in waterjet cutting, "sand" blasting, sandpaper, water filtration, and a number of other uses. Almandine is the hardest garnet and also the most abundant. It is the garnet of choice for most abrasive applications. Photo by the United States Geological Survey.
Garnet crystal: Almandine, a variety of garnet from River Valley, Ontario, Canada. This specimen is a nice euhedral crystal approximately 2 inches (5 centimeters) across. These types of crystals are often weathered out of a garnet-bearing mica schist and are transported by streams.
Almandine garnet: Almandine, a variety of garnet from Lount Township, Ontario, Canada. This is a granular specimen approximately 11.4 centimeters across.
Garnet peridotite: Garnet peridotite from Alpe Arami, near Bellinzona, Switzerland. The material in this rock originated within Earth's mantle and was delivered to the surface through a volcanic pipe during a deep-source volcanic eruption. The garnets are the reddish purple grains within the rock. Garnets weathered from such pipes often serve as indicator minerals when exploring for volcanic pipes that might contain diamond. Public domain photo by Woudloper.
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