HISTORY OF CHEMICAL MATCHES - Many chemical reactions generate heat and fire, but matches are a fairly recent invention. Brand was an Hamburg alchemist who discovered phosphorus during his attempts to turn base metals into gold. Knuckel successfully made phosphorus from urine. Sir Robert Boyle coated a piece of paper with phosphorus, with a separate splinter of sulfur-coated wood. When the wood was drawn through the paper, it would burst into flame. The Diamond Match Company got a patent for a non-poisonous match which used sesquisulfide of phosphorus. Butane lighters have largely replaced matches in many part of the world, however matches are still made and used. The Diamond Match Company, for example, makes more than 12 billion matches a year. Approximately 500 billion matches are used annually in the United States.

......................................................................................................................................

History of Chemical Matches

Chemistry of Making Fire Using Matches

by Anne Marie Helmenstine, Ph.D. 

If you need to start a fire do you rub sticks together or break out your handy flint? Probably not.

Most people would use a lighter or a match to start a fire. Matches allow for a portable, easy-to-use source of fire.

Many chemical reactions generate heat and fire, but matches are a fairly recent invention.

Matches are also an invention you probably wouldn't choose to duplicate if civilization ended today or you were stranded on a desert island.

The chemicals involved in modern matches are generally safe, but that wasn't always the case:

1669 [Hennig Brand or Brandt, also known as Dr. Teutonicus]

Brand was an Hamburg alchemist who discovered phosphorus during his attempts to turn base metals into gold.

He allowed a vat of urine to stand until it putrefied. He boiled the resulting liquid down to a paste, which he heated to a high temperature, so that the vapors could be drawn into water and condensed into... gold.

Brand didn't get gold, but he did obtain a waxy white substance that glowed in the dark. This was phosphorus, one of the first elements to be isolated other than those which exist free in nature.

Evaporating urine produced ammonium sodium hydrogen phosphate (microcosmic salt), which yielded sodium phosphite upon heating. When heated with carbon (charcoal) this decomposed into white phosphorus and sodium pyrophosphate:

(NH₄)NaHPO₄ —› NaPO₃ + NH₃ + H₂O
8NaPO₃ + 10C —› 2Na₄P₂O₇ + 10CO + P₄

Although Brand tried to keep his process a secret, he sold his discovery to a German chemist, Krafft, who exhibited phosphorus throughout Europe.

Word leaked out that the substance was made from urine, which was all Kunckel and Boyle needed to work out their own means of purifying phosphorus.

1678 [Johann Kunckel]
Knuckel successfully made phosphorus from urine.

1680 [Robert Boyle]

Sir Robert Boyle coated a piece of paper with phosphorus, with a separate splinter of sulfur-coated wood. When the wood was drawn through the paper, it would burst into flame.

Phosphorus was difficult to obtain at that time, so the invention was only a curiosity.

Boyle's method of isolating phosphorus was more efficient than Brand's:

4NaPO₃ + 2SiO₂ + 10C —› 2Na₂SiO₃ + 10CO + P₄

1826/1827 [John Walker, Samuel Jones]

Walker serendipitously discovered a friction match made from antimony sulfide, potassium chlorate, gum, and starch, resulting from a dried blob on the end of a stick used to stir a chemical mixture.

He didn't patent his discovery, though he did show it to people.

Samuel Jones saw the demonstration and started to produce 'Lucifers', which were matches marketed to the Southern and Western U.S. states.

Lucifers reportedly could ignite explosively, sometimes throwing sparks at a considerable distance. They were known to have a strong 'firework' odor.

1830 [Charles Sauria]

Sauria reformulated the match using white phosphorus, which eliminated the strong odor. However, the phosphorus was deadly.

Many people developed a disorder known as 'phossy jaw'. Children who sucked on matches developed skeletal deformities. Phosphorus factory workers got bones diseases. One pack of matches contained enough phosphorus to kill a person.

1892 [Joshua Pusey]

Pusey invented the matchbook, however, he placed the striking surface on the inside of the book so that all 50 matches would ignite at once.

The Diamond Match Company later purchased Pusey's patent and moved the striking surface to the exterior of the packaging.

1910 [Diamond Match Company]

With a worldwide push to ban the use of white phosphorus matches, the Diamond Match Company got a patent for a non-poisonous match which used sesquisulfide of phosphorus.

U.S. President Taft requested that Diamond Match give up their patent.

1911 [Diamond Match Company]

Diamond yielded their patent on January 28, 1911. Congress passed a law placing a prohibitively high tax on white phosphorus matches.

Present Day

Butane lighters have largely replaced matches in many part of the world, however matches are still made and used.

The Diamond Match Company, for example, makes more than 12 billion matches a year. Approximately 500 billion matches are used annually in the United States.

An alternative to chemical matches is fire steel. Fire steel uses a striker and magnesium metal to produce sparks which may be used to start a fire.

Anne Marie Helmenstine, Ph.D.

Introduction

Ph.D. in biomedical sciences from the University of Tennessee at Knoxville - Oak Ridge National Laboratory.

Science educator with experience teaching chemistry, biology, astronomy, and physics at the high school, college, and graduate levels.

ThoughtCo and About Education chemistry expert since 2001.

Widely-published graphic artist, responsible for printable periodic tables and other illustrations used in science.

Experience

Anne Helmenstine, Ph.D. has covered chemistry for ThoughtCo and About Education since 2001, and other sciences since 2013. She taught chemistry, biology, astronomy, and physics at the high school, college, and graduate levels. She has worked as a research scientist and also abstracting and indexing diverse scientific literature for the Department of Energy.

In addition to her work as a science writer, Dr. Helmenstine currently serves as a scientific consultant, specializing in problems requiring an interdisciplinary approach. Previously, she worked as a research scientist and college professor. 

Education

Dr. Helmenstine holds a Ph.D. in biomedical sciences from the University of Tennessee at Knoxville and a B.A. in physics and mathematics with a minor in chemistry from Hastings College. In her doctoral work, Dr. Helmenstine developed ultra-sensitive chemical detection and medical diagnostic tests.

ThoughtCo and Dotdash

ThoughtCo is a premier reference site focusing on expert-created education content. We are one of the top-10 information sites in the world as rated by comScore, a leading Internet measurement company. Every month, more than 13 million readers seek answers to their questions on ThoughtCo.

For more than 20 years, Dotdash brands have been helping people find answers, solve problems, and get inspired. We are one of the top-20 largest content publishers on the Internet according to comScore, and reach more than 30% of the U.S. population monthly. Our brands collectively have won more than 20 industry awards in the last year alone, and recently Dotdash was named Publisher of the Year by Digiday, a leading industry publication.

https://www.thoughtco.com/history-of-chemical-matches-606805